4 Ergebnisse.

Keine Beschreibung.

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effec...

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched.

The past two decades have witnessed phenomenal advances in the synthetic, biological, and medicinal applications of organoboronic acid derivatives. In particular, a large number of novel synthetic processes have signifi cantly expanded the breadth of usefulness of boronic acids as a class of substrates. As a result, most chemists in academia and industry now make use of boronic acids in synthetic chemistry, be it for Suzuki-Miyaura cross-coupl...