This thesis reports on innovations in the design and direct synthesis of graphene-based woven fabric (GWF) and multi-layer graphene/porous carbon woven fabric films (MLG/PC) by means of chemical vapor deposition (CVD), using woven copper mesh and nickel mesh as the template. Further, it presents the successful applications of these materials as a platform for solar cells, supercapacitors and sensors, making it especially of interest to researchers and graduate students in the fields of materials sciences, nanotechnology and renewable energy.